MasteryExams
General Science • ChemistryMedium

What is the primary function of sulfur in the vulcanization of natural rubber?

A. To act as a solvent that dissolves the polymer chains
B. To form cross-links between polyisoprene chains, improving elasticity and strength✓ Correct Answer
C. To accelerate the natural degradation of rubber products
D. To impart permanent white color to the rubber compound

💡 Solution & Explanation

Vulcanization involves heating natural rubber with sulfur, which creates cross-links between adjacent polyisoprene polymer chains. This chemical modification significantly enhances tensile strength, elasticity, and resistance to temperature fluctuations. Without cross-linking, natural rubber becomes sticky when warm and brittle when cold. Charles Goodyear discovered this transformative industrial process in the nineteenth century.

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