MasteryExams
General Science • ChemistryHard

Which organic reaction involves the conversion of a primary amine into an isocyanide (carbylamine) by heating with chloroform and alcoholic potassium hydroxide?

A. Reimer-Tiemann reaction
B. Carbylamine test✓ Correct Answer
C. Cannizzaro reaction
D. Aldol condensation

💡 Solution & Explanation

The carbylamine reaction is a definitive chemical test for identifying primary amines by heating them with chloroform and alcoholic potassium hydroxide to produce offensive-smelling isocyanides. The Reimer-Tiemann reaction is instead used for the ortho-formylation of phenols to produce hydroxybenzaldehydes like salicylaldehyde.

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