MasteryExams
General Science • ChemistryHard

What is the principal reason why transition metals exhibit variable oxidation states in their chemical compounds?

A. The complete shielding of outer d-electrons by inner s-orbitals
B. The very small energy difference between (n minus 1) d-orbitals and ns-orbitals✓ Correct Answer
C. Their extremely high electronegativity values across all periods
D. The total absence of unpaired electrons in their ground state atomic configurations

💡 Solution & Explanation

Transition elements possess valence electrons in both the outermost s-orbital and the penultimate d-orbital. Because the energy difference between these orbitals is remarkably small, electrons from both levels can participate in chemical bonding, allowing atoms to exhibit multiple stable oxidation states. Large electronegativity or complete shielding would prevent this flexible electron participation. Variable oxidation states allow transition metal ions to function effectively as homogeneous and heterogeneous catalysts.

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