MasteryExams
General Science • ChemistryHard

Which of the following thermodynamic relations correctly defines Gibbs free energy change at constant temperature and pressure?

A. Delta G equals Delta H plus T Delta S
B. Delta G equals Delta H minus T Delta S✓ Correct Answer
C. Delta G equals T Delta H minus Delta S
D. Delta G equals Delta U plus P Delta V

💡 Solution & Explanation

Gibbs free energy change is defined at constant temperature and pressure as the enthalpy change minus the product of absolute temperature and entropy change, expressed as Delta G equals Delta H minus T Delta S. A negative value of Delta G indicates a spontaneous thermodynamic process, while a positive value indicates non-spontaneity. This master equation links the first and second laws of thermodynamics into a single criterion for chemical equilibrium.

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